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Researchers also found that intracellular GSH is involved in protecting human skin cells against a wide range of solar radiation damage from the sun

10.1038/s41569-018-0064-2 Nat Rev Cardiol

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Because of that, plants developed complexed ROS control system based on enzymes (like glutathione reductase-GR, glutathione S-transferase-GST, glutathione peroxidase-GPX) and scavenging non-enzymatic hydrophilic molecules like ascorbate (AsA) and glutathione (GSH) (Noctor and Foyer, 1998)